Copper‐Mediated Reversible Deactivation Radical Polymerization in Aqueous Media,Angewandte Chemie International Edition

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Copper‐Mediated Reversible Deactivation Radical Polymerization in Aqueous Media
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-07-16 , DOI: 10.1002/anie.201802091
Glen R. Jones ₁ , Athina Anastasaki ₂ , Richard Whitfield ₁ , Nikolaos Engelis ₁ , Evelina Liarou ₁ , David M. Haddleton ₁

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Key advances within the past 10 years have transformed copper‐mediated radical polymerization from a technique which was not very tolerant of protic media into a range of closely related processes capable of controlling the polymerization of a wide range of monomers in pure water at ppm catalyst loadings. This approach has afforded water‐soluble macromolecules of desired molecular weight, architecture, and chemical functionality, with applications ranging from drug delivery to oil processing. In this Review we highlight and critically evaluate the synthetic methods that have been developed to control radical polymerization in water by using copper complexes as well as identify future areas of interest and challenges still to be overcome.

中文翻译：

水性介质中铜介导的可逆失活自由基聚合

过去10年中的主要进展已将铜介导的自由基聚合反应从一种对质子介质不太耐受的技术转变为一系列密切相关的过程，这些过程能够控制ppm催化剂负载下纯水中多种单体的聚合。这种方法提供了具有所需分子量，结构和化学功能的水溶性大分子，其应用范围从药物输送到石油加工。在本综述中，我们重点介绍并批判性地评估了已开发出的合成方法，该方法通过使用铜络合物来控制水中的自由基聚合反应，并确定了未来的关注领域和仍需克服的挑战。

更新日期：2018-07-16

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