Graphene oxide (GO) membranes, as laminated and channel-rich architectures assembled by stacked GO nanosheets, have surpassed other two-dimensional (2D) nanomaterials and present preeminent structural specialization and potential applicability in a wide range of environmental applications. This review mainly surveys the latest GO-based macroscopic membranes, which feature distinct functionalized structures, interior fluid flows, and tunable physicochemical properties. The GO-based membranes are classified and presented in three typical forms: single-layered porous GO membranes, few-layered laminated GO membranes, and multi-layered composited GO membranes. More attention is paid to target-oriented preparation strategies for the assembly of GO building blocks, involving multiple interactions and technical advantages, and to the resulting membrane characteristics. The overview also explores the serviceability of these GO-based membranes for full-scale use in environmental practices in gas, water, and biological treatments to pave the way for the promising development and realization of their prospects.

氧化石墨烯（GO）膜是由堆叠的GO纳米片组装而成的层状和富通道结构，已经超越了其他二维（2D）纳米材料，并在各种环境应用中展现出卓越的结构专业性和潜在适用性。这篇综述主要调查了最新的基于GO的宏观膜，这些膜具有独特的功能化结构，内部流体流动和可调节的理化特性。基于GO的膜被分类并以三种典型形式呈现：单层多孔GO膜，少层层压GO膜和多层复合GO膜。越来越多地关注GO构建模块组装的面向目标的准备策略，其中涉及多种交互作用和技术优势，以及最终的膜特性。概述还探讨了这些基于GO的膜在天然气，水和生物处理等环境实践中的全面使用的可维修性，从而为有希望的发展和实现其前景铺平了道路。