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Hierarchical nanocrystalline NiO with coral-like structure derived from nickel galactarate dihydrate: An active mesoporous catalyst for methyl ethyl ketone production
Arabian Journal of Chemistry ( IF 6 ) Pub Date : 2018-04-14
Samih A. Halawy, Mohamed A. Mohamed, Adel Abdelkader

Nanocrystalline NiO with a coral-like structure (38 nm) has been prepared via thermal decomposition of a new precursor, nickel galactarate (NiC6H8O8·2H2O), at 500 °C for 3 h in air. Thermal decomposition of that precursor was studied by TG and DSC techniques. The resultant NiO was physicochemically characterized by XRD, FTIR, SEM, surface area, porosity and CO2-TPD. NiO was found to exhibit a remarkable activity towards the synthesis of MEK from 2-butanol between 200 and 325 °C. In addition, it has shown a great tendency to ease regeneration of the used catalyst after 192 h in stream by simple refreshing method.



中文翻译:

由半水合半乳糖酸镍生成的具有珊瑚状结构的分层纳米晶体NiO:用于生产甲乙酮的活性介孔催化剂

通过在空气中在500°C下热分解一种新的前驱体半乳糖酸镍(NiC 6 H 8 O 8 ·2H 2 O)制备了具有珊瑚状结构(38 nm)的纳米晶NiO 。通过TG和DSC技术研究了该前体的热分解。通过XRD,FTIR,SEM,表面积,孔隙率和CO 2 -TPD对所得的NiO进行物理化学表征。发现NiO在200至325°C的温度下对由2-丁醇合成MEK表现出显着的活性。另外,已经显示出很大的趋势,即通过简单的刷新方法在流过192小时后易于使用过的催化剂再生。

更新日期:2018-04-25
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