Stereodivergent Catalysis,Chemical Reviews

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Stereodivergent Catalysis
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-04-20 00:00:00 , DOI: 10.1021/acs.chemrev.7b00561
Irina P. Beletskaya ₁ , Carmen Nájera ₂ , Miguel Yus ₂

Affiliation

This review covers diastereo- and enantiodivergent catalyzed reactions in acyclic and cyclic systems using metal complexes or organocatalysts. Among them, nucleophilic addition to carbon–carbon and carbon–nitrogen double bonds, α-functionalization of carbonyl compounds, allylic substitutions, and ring opening of oxiranes and aziridines are considered. The diastereodivergent synthesis of alkenes from alkynes is also included. Finally, stereodivergent intramolecular and intermolecular cycloadditions and other cyclizations are also reported.

中文翻译：

立体发散催化

这篇综述涵盖了使用金属配合物或有机催化剂在非环状和环状体系中的非对映和对映体催化反应。其中，考虑了碳-碳和碳-氮双键的亲核加成，羰基化合物的α-官能化，烯丙基取代以及环氧乙烷和氮丙啶的开环。还包括从炔烃的非对映异构体的烯烃合成。最后，还报道了立体发散的分子内和分子间环加成和其他环化。

更新日期：2018-04-20

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