Convergent Assembly of Enantioenriched Tetrahydrobenzofuro[2,3‐b]pyrrole Scaffolds by AgI‐Catalyzed Asymmetric Domino Reaction of Isocyanoacetates,Asian Journal of Organic Chemistry

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Convergent Assembly of Enantioenriched Tetrahydrobenzofuro[2,3‐b]pyrrole Scaffolds by AgI‐Catalyzed Asymmetric Domino Reaction of Isocyanoacetates
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-05-03 , DOI: 10.1002/ajoc.201800222
Hengguang Cheng ₁ , Runmei Zhang ₁ , Min Wang ₁ , Xiaofei Zeng ₁ , Chunsong Xie ₁

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In the presence of cinchona‐derived chiral phosphine ligands, enantioenriched tetrahydrobenzofuro[2,3‐b]pyrroles can be efficiently assembled by a mild, convergent and atom‐economic Ag^I‐catalyzed asymmetric domino reaction of readily available isocyanoacetates and 2‐(2‐hydroxyphenyl)acrylates.

中文翻译：

AgI催化异氰酸酯的不对称多米诺反应，对映富集四氢苯并呋喃并[2,3-b]吡咯支架的组装

在存在金鸡纳菌衍生的手性膦配体的情况下，对映体富集的四氢苯并呋喃[2,3- b ]吡咯可以通过温和，会聚且原子经济的Ag ^I催化的不对称多米诺反应有效地组装，该反应易得的异氰基乙酸盐和2-（2 -羟基苯基）丙烯酸酯。

更新日期：2018-05-03

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