Ferrocenyl Phthalocyanine as Donor in Non‐Poly(3‐hexylthiophen‐2,5‐diyl) Bulk Heterojunction Solar Cell,Chemistry - A European Journal

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Ferrocenyl Phthalocyanine as Donor in Non‐Poly(3‐hexylthiophen‐2,5‐diyl) Bulk Heterojunction Solar Cell
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-04-20 , DOI: 10.1002/chem.201801340
Ilgın Nar ₁ , Armağan Atsay ₁ , Ahmet Altındal ₂ , Esin Hamuryudan ₁ , Makbule B. Koçak ₁ , Ahmet Gül ₁

Affiliation

Bulk heterojunction (BHJ) solar cells might one day play a vital role in realizing low‐cost and environmentally benign photovoltaic devices. In this work, a BHJ solar cell was designed, based on a hexadeca‐substituted phthalocyanine (FcPc) with ferrocenyl linked to the phthalocyanine ring. Next, we sought to obtain more quantitative information about the usability of this newly synthesized compound as a donor material in BHJ solar cells. Thus, BHJs with the structure of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/FcPc:[6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) blend/LiF/Al were fabricated and characterized. The effect of blend ratio (0.5–2.0) on the BHJ solar cell parameters was also investigated. Interesting results were obtained in FcPc and the PCBM blend‐based BHJ solar cell under optimized conditions. Our results presented here demonstrate that BHJ devices employing FcPc as a donor has great potential for the development of highly efficient non‐poly(3‐hexylthiophen‐2,5‐diyl) photovoltaic devices.

中文翻译：

二茂铁酞菁在非聚（3-己基噻吩-2,5-二基）本体异质结太阳能电池中作为给体

整块异质结（BHJ）太阳能电池有一天可能在实现低成本和对环境无害的光伏设备中起至关重要的作用。在这项工作中，基于十六烷基取代的酞菁（FcPc）设计了BHJ太阳能电池，其中二茂铁基连接到酞菁环上。接下来，我们寻求获得更多有关此新合成的化合物作为BHJ太阳能电池供体材料的可用性的定量信息。因此，具有氧化铟锡/聚（3,4-乙撑二氧噻吩）：聚（苯乙烯磺酸盐）/ FcPc：[6,6]-苯基-C61-丁酸甲酯（PCBM）的结构的BHJ共混物/制备并表征了LiF / Al。还研究了混合比（0.5–2.0）对BHJ太阳能电池参数的影响。在优化条件下，FcPc和基于PCBM共混物的BHJ太阳能电池获得了有趣的结果。我们在这里提出的结果表明，采用FcPc作为供体的BHJ器件在开发高效非聚（3-己基噻吩-2,5-二基）光伏器件方面具有巨大潜力。

更新日期：2018-04-20

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