Electrochemical Aziridination by Alkene Activation Using a Sulfamate as the Nitrogen Source,Angewandte Chemie International Edition

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Electrochemical Aziridination by Alkene Activation Using a Sulfamate as the Nitrogen Source
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-04-20 , DOI: 10.1002/anie.201801106
Jin Li ₁ , Wenhao Huang ₁ , Jingzhi Chen ₁ , Lingfeng He ₁ , Xu Cheng _{1,

2,

3} , Guigen Li _{1,

4}

Affiliation

The first direct aziridination of triaryl‐substituted alkenes was achieved by means of an electrochemical process that could extend to multisubstituted styrenes. Specifically, hexafluoroisopropanol sulfamate was used as a nucleophilic nitrogen source. Mechanistic experiments suggest that this electrochemical process proceeds by stepwise formation of two C−N bonds through reactions between cationic carbon species and the sulfamate.

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