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Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-04-20 , DOI: 10.1002/anie.201802310
Yoshiya Sekiguchi 1 , Kazuya Arashiba 1 , Hiromasa Tanaka 2 , Aya Eizawa 1 , Kazunari Nakajima 1 , Kazunari Yoshizawa 2 , Yoshiaki Nishibayashi 1
Affiliation  

Newly designed and prepared vanadium complexes bearing anionic pyrrole‐based PNP‐type pincer and aryloxy ligands were found to work as effective catalysts for the direct conversion of molecular dinitrogen into ammonia and hydrazine under mild reaction conditions. This is the first successful example of vanadium‐catalyzed dinitrogen reduction under mild reaction conditions.

中文翻译:

钒配合物催化分子氮还原为氨和肼

发现新设计和制备的带有阴离子吡咯基PNP型钳和芳氧基配体的钒配合物可作为有效的催化剂,在温和的反应条件下将分子中的二氮直接转化为氨和肼。这是在温和的反应条件下钒催化的二氮还原的第一个成功实例。
更新日期:2018-04-20
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