Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes,Angewandte Chemie International Edition

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Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-04-20 , DOI: 10.1002/anie.201802310
Yoshiya Sekiguchi ₁ , Kazuya Arashiba ₁ , Hiromasa Tanaka ₂ , Aya Eizawa ₁ , Kazunari Nakajima ₁ , Kazunari Yoshizawa ₂ , Yoshiaki Nishibayashi ₁

Affiliation

Newly designed and prepared vanadium complexes bearing anionic pyrrole‐based PNP‐type pincer and aryloxy ligands were found to work as effective catalysts for the direct conversion of molecular dinitrogen into ammonia and hydrazine under mild reaction conditions. This is the first successful example of vanadium‐catalyzed dinitrogen reduction under mild reaction conditions.

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