Site-selectivity in the halogenation of titanium-functionalized polyoxovanadate–alkoxide clusters†,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Site-selectivity in the halogenation of titanium-functionalized polyoxovanadate–alkoxide clusters†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-04-20 00:00:00 , DOI: 10.1039/c8cc01517a
L. E. VanGelder _{1,

2,

3,

4} , P. L. Forrestel _{1,

2,

3,

4} , W. W. Brennessel _{1,

2,

3,

4} , E. M. Matson _{1,

2,

3,

4}

Affiliation

Herein, we report the synthesis and characterization of a dititanium-functionalized polyoxovanadate–alkoxide cluster. The incorporation of a second heterometal within the cluster core results in striking differences in reactivity of the multimetallic complex. Chlorination of the metal oxide cluster is reported, revealing the directing role of titanium in M–O bond cleavage.

中文翻译：