Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates,Synlett

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Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates
Synlett ( IF 1.7 ) Pub Date : 2018-04-18 , DOI: 10.1055/s-0036-1591974
Mao Chen ₁ , Honghong Gong ₁ , Yu Gu ₁

Affiliation

Fluorinated polymers are important materials for applications in many areas. This article summarizes the development of controlled/living radical polymerization (CRP) of semifluorinated (meth)acrylates, and briefly introduces their reaction mechanisms. While the classical CRP such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and nitroxide-mediated radical polymerization (NMP) have promoted the preparation of semifluorinated polymers with tailor-designed architectures, recent development of photo-CRP has led to unprecedented accuracy and monomer scope. We expect that synthetic advances will facilitate the engineering of advanced fluorinated materials with unique properties. 1 Introduction 2 Atom Transfer Radical Polymerization 3 Reversible Addition-Fragmentation Chain Transfer Polymerization 4 Nitroxide-Mediated Radical Polymerization 5 Photo-CRP Mediated with Metal Complexes 6 Metal-free Photo-CRP 7 Conclusion

中文翻译：

半氟化（甲基）丙烯酸酯的可控/活性自由基聚合

氟化聚合物是许多领域应用的重要材料。本文综述了半氟化（甲基）丙烯酸酯可控/活性自由基聚合（CRP）的研究进展，并简要介绍了它们的反应机理。虽然经典的 CRP，如原子转移自由基聚合 (ATRP)、可逆加成断裂链转移 (RAFT) 聚合和氮氧介导的自由基聚合 (NMP) 促进了具有定制设计结构的半氟化聚合物的制备，但最近光-CRP 导致了前所未有的准确性和单体范围。我们预计合成方面的进步将促进具有独特性能的先进氟化材料的工程设计。

更新日期：2018-04-18

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