Continuous Flow Conversion of Biomass-Derived Methyl Levulinate into γ-Valerolactone Using Functional Metal Organic Frameworks,ACS Sustainable Chemistry & Engineering

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Continuous Flow Conversion of Biomass-Derived Methyl Levulinate into γ-Valerolactone Using Functional Metal Organic Frameworks
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-04-17 00:00:00 , DOI: 10.1021/acssuschemeng.8b00549
Weiyi Ouyang ₁ , Deyang Zhao ₂ , Yantao Wang ₂ , Alina M. Balu ₁ , Christophe Len _{2,

3} , Rafael Luque _{1,

4}

Affiliation

The zirconium-based metal organic framework, UiO-66 (Zr), was successfully synthesized via solvothermal method, followed by various characterization including XRD, thermal analysis, N₂ physisorption, and TEM. As-synthesized UiO-66 (Zr) was employed in the transformation of methyl levulinate (ML) to γ-valerolactone (GVL) via catalytic transfer hydrogenation (CTH) under continuous flow and various reaction conditions, which gave superior catalytic performance and efficiency as compared to reported catalysts. The obtained results show great potential of applying UiO-66 (Zr) in upgrading biomass derivatives to useful biofuel/chemical products, paving the way for green energy production from renewable resources.

中文翻译：

使用功能金属有机骨架将生物质衍生的乙酰丙酸甲酯连续流转化为γ-戊内酯

通过溶剂热法成功合成了锆基金属有机骨架UiO-66（Zr），然后进行了包括XRD，热分析，N ₂物理吸附和TEM在内的各种表征。合成后的UiO-66（Zr）在连续流动和各种反应条件下通过催化转移加氢（CTH）将乙酰丙酸甲酯（ML）转化为γ-戊内酯（GVL），具有优异的催化性能和效率。与报道的催化剂相比。获得的结果表明，使用UiO-66（Zr）将生物质衍生物升级为有用的生物燃料/化学产品具有巨大潜力，为从可再生资源生产绿色能源铺平了道路。

更新日期：2018-04-17

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