Photoinduced ring-opening polymerisation of l-lactide via a photocaged superbase†,Chemical Communications

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Photoinduced ring-opening polymerisation of l-lactide via a photocaged superbase†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-04-17 00:00:00 , DOI: 10.1039/c8cc01913d
P. K. Kuroishi _{1,

2,

3,

4,

5} , A. P. Dove _{4,

5,

6,

7}

Affiliation

The phototriggered ring-opening polymerisation of L-lactide is demonstrated for the first time using a photocaged tetramethylguanidine. The catalytic activity of the free guanidine was also investigated, showing it to be active for the polymerisation of δ-valerolactone and ε-caprolactone in the presence of a thiourea cocatalyst.

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