This review covers compounds formed by Mannich-like reactions of coordinated amine-compounds with an α-methylene nitro-compound (usually nitroethane) and an aldehyde (predominantly formaldehyde) to form a compound with two primary amine functions joined by a –NH–(CH₂)–C(NO₂)(CH₃)–(CH₂)–NH– link, forming a new chelate ring. Most reported compounds have tetraaza-macrocyclic ligands. Copper(II) is the usual “templating” metal ion, with compounds of nickel(II), palladium(II), platinum(II) and gold(III) also reported. The refcodes of compound with structures in the Cambridge Crystallographic Data Centre files are listed and structural figures of representative examples shown.

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这篇综述涵盖了由配位胺化合物与α-亚甲基硝基化合物（通常为硝基乙烷）和醛（主要为甲醛）的曼尼希式反应形成的化合物，该化合物形成具有两个伯胺官能团的-NH-（ CH ₂）–C（NO ₂）（CH ₃）–（CH ₂）–NH–连接，形成一个新的螯合环。大多数报道的化合物具有四氮杂-大环配体。铜（II）是通常的“模板”金属离子，还报道了镍（II），钯（II），铂（II）和金（III）的化合物。列出了剑桥晶体数据中心文件中具有结构的化合物的参考代码，并显示了代表性示例的结构图。

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