Regiospecific alkyl addition of (hetero)arene-fused thiophenes enabled by a visible-light-mediated photocatalytic desulfuration approach†,Chemical Communications

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Regiospecific alkyl addition of (hetero)arene-fused thiophenes enabled by a visible-light-mediated photocatalytic desulfuration approach†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-04-13 00:00:00 , DOI: 10.1039/c8cc02052c
Jiamei Di _{1,

2,

3,

4,

5} , Huan He _{1,

2,

3,

4,

5} , Falu Wang _{1,

2,

3,

4,

5} , Fei Xue _{1,

2,

3,

4,

5} , Xiao-Yu Liu _{1,

2,

3,

4,

5} , Yong Qin _{1,

2,

3,

4,

5}

Affiliation

A photoredox-mediated, regiospecific alkyl addition reaction of (hetero)arene-fused thiophenes has been developed, employing bench-stable N-benzoyl alkyl-sulfinamides as the alkyl sources. This protocol offers a unique desulfuration approach to generate alkyl radicals that proceeds via nitrogen-centered radical intermediates.

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