Well defined difluorogold(iii) complexes supported by N-ligands†,Chemical Communications

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Well defined difluorogold(iii) complexes supported by N-ligands†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-04-12 00:00:00 , DOI: 10.1039/c8cc02535e
Mohammad Albayer _{1,

2,

3} , Robert Corbo _{1,

2,

3} , Jason L. Dutton _{1,

2,

3}

Affiliation

Stable difluorogold(III) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(I) precursors using XeF₂ or from tricationic Au(III) precursors by displacement of the N-ligands using fluoride from economical KF. X-ray crystallographic studies of the bisimidazole ligated derivative shows the shortest Au–F bond known in a gold complex.

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