Copper-Catalyzed Oxidative Carbon–Carbon and/or Carbon–Heteroatom Bond Formation with O2 or Internal Oxidants,Accounts of Chemical Research

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Copper-Catalyzed Oxidative Carbon–Carbon and/or Carbon–Heteroatom Bond Formation with O2 or Internal Oxidants
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-04-12 00:00:00 , DOI: 10.1021/acs.accounts.7b00611
Xiaodong Tang ₁ , Wanqing Wu ₁ , Wei Zeng ₁ , Huanfeng Jiang ₁

Affiliation

Selective oxidation, a fundamental organic transformation of critical importance, produces value-added products from simple organic molecules. This process is extensively used to incorporate heteroatoms into carbon-based molecules, where high-valent metal salts, hypervalent halogen reagents, and peroxides are widely used as oxidants. Oxidation reactions are extremely challenging because their selectivity is hard to control and/or they form significant quantities of unwanted waste derived from the stoichiometric oxidants. Undoubtedly, the utilization of green oxidants such as molecular oxygen (O₂) or internal oxidants provides tunable oxidation abilities and produces no environmentally hazardous byproducts. Thus, synthetic chemists have devoted increasing attention to the utilization of green oxidants to obtain valuable products.

中文翻译：

铜催化的O ₂或内部氧化剂形成的碳-碳和/或碳-杂原子键

选择性氧化是至关重要的基础有机转化，它可以通过简单的有机分子生产出增值产品。该方法被广泛用于将杂原子掺入碳基分子中，其中高价金属盐，高价卤素试剂和过氧化物被广泛用作氧化剂。氧化反应极具挑战性，因为它们的选择性很难控制和/或形成大量源自化学计量氧化剂的有害废物。毫无疑问，绿色氧化剂的利用，例如分子氧（O ₂）或内部氧化剂提供可调节的氧化能力，并且不会产生对环境有害的副产物。因此，合成化学家已经越来越关注使用绿色氧化剂来获得有价值的产品。

更新日期：2018-04-12

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