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Large strain response with low driving field in Bi1/2Na1/2TiO3–Bi1/2K1/2TiO3–Bi(Mg2/3Nb1/3)O3 ceramics
Journal of the American Ceramic Society ( IF 3.9 ) Pub Date : 2018-04-19 , DOI: 10.1111/jace.15589
Guangzhi Dong 1 , Huiqing Fan 1 , Jing Shi 2 , Qiang Li 1
Affiliation  

The (1−x)(0.8Bi1/2Na1/2TiO3–0.2Bi1/2K1/2TiO3)−xBiMg2/3Nb1/3O3 (100xBMN) ternary solid solutions were designed and prepared using a conventional solid‐state reaction. Temperature and compositional dependent ferroelectric, piezoelectric, dielectric features, and structural evolution were systematically studied. At the critical composition of 2BMN, a large bipolar strain of 0.43% was achieved at 55 kV/cm, and the normalized strain reaches to 862 pm/V at a low driving electric field of 40 kV/cm. It was found that the substitution of BiMg2/3Nb1/3O3 induces a transformation from ferroelectric to relaxor phase by disrupting the long range ferroelectric order. Therefore, as the external electric field was applied, a relaxor‐ferroelectric phase transition will be induced. This is contributed to the giant strain. The results above suggest that such a ternary composition is a promising candidate for application to actuator.

中文翻译:

Bi1 / 2Na1 / 2TiO3–Bi1 / 2K1 / 2TiO3–Bi(Mg2 / 3Nb1 / 3)O3陶瓷的大应变响应和低驱动场

(1- x)(0.8Bi 1/2 Na 1/2 TiO 3 –0.2Bi 1/2 K 1/2 TiO 3-x BiMg 2/3 Nb 1/3 O 3(100 xBMN)三元固溶体是使用常规固相反应设计和制备的。系统地研究了温度和成分相关的铁电,压电,介电特性和结构演变。在2BMN的临界组成下,在55 kV / cm时实现了0.43%的大双极应变,在40 kV / cm的低驱动电场下,归一化应变达到862 pm / V。发现BiMg 2/3 Nb 1/3 O 3的取代通过破坏长距离铁电有序,从而引起从铁电到弛豫相的转变。因此,当施加外部电场时,将引发弛豫铁电相变。这造成了巨大的压力。以上结果表明,这种三元组成是应用于致动器的有希望的候选者。
更新日期:2018-04-19
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