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Electrochemically synthesised xanthone-cored conjugated polymers as materials for electrochromic windows
Electrochimica Acta ( IF 5.5 ) Pub Date : 2018-04-11
H.F. Higginbotham, M. Czichy, B.K. Sharma, A.M. Shaikh, R.M. Kamble, P. Data

In this work, we present the electrochemical polymerisation process of triarylamine-xanthone derivatives and behaviour of the formed polymers using various potentiodynamic techniques. The formed electropolymers have limited conjugation but show very promising electrochromic behaviour. Furthermore, by coupling the electrochemical analysis with each polymer's spectroscopic output, we were able to evaluate doping processes and the type of charge carriers formed. Through careful analysis, we were able to describe the electropolymerisation process and formed triarylamine-based polyxanthone derivatives. The polymers were found to exhibit good stability and good colouration efficiency to suggesting that they have potential application in electrochromic devices.



中文翻译:

电化学合成的以蒽酮为核心的共轭聚合物作为电致变色窗的材料

在这项工作中,我们介绍了三芳基胺-x吨酮衍生物的电化学聚合过程以及使用各种电位动力学技术形成的聚合物的行为。形成的电聚合物具有有限的共轭,但是显示出非常有前途的电致变色行为。此外,通过将电化学分析与每种聚合物的光谱输出耦合,我们能够评估掺杂过程和形成的电荷载流子的类型。通过仔细的分析,我们能够描述电聚合过程并形成了基于三芳基胺的聚poly吨酮衍生物。发现该聚合物表现出良好的稳定性和良好的着色效率,表明它们在电致变色器件中具有潜在的应用。

更新日期:2018-04-12
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