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The first synthesis of biatriosporin D
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-04-11 , DOI: 10.1016/j.tetlet.2018.04.027 Shuai Wang , George A. Kraus
中文翻译:
biatriosporin D的首次合成
更新日期:2018-04-11
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-04-11 , DOI: 10.1016/j.tetlet.2018.04.027 Shuai Wang , George A. Kraus
Biatriosporin D was synthesized in six steps from 3,5-dimethoxyphenol. The key step was an intramolecular Friedel-Crafts cyclization of an acyl imidazolide to form an ortho-quinone.
中文翻译:
biatriosporin D的首次合成
由3,5-二甲氧基苯酚以六步合成BiatriosporinD。关键步骤是酰基咪唑啉化物的分子内Friedel-Crafts环化反应,从而形成邻醌。