Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates.,ChemPlusChem

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Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates.
ChemPlusChem ( IF 3.0 ) Pub Date : 2018-04-25 , DOI: 10.1002/cplu.201800131
Ashot Gevorgyan _{1,

2} , Satenik Mkrtchyan ₁ , Tatevik Grigoryan ₁ , Viktor O Iaroshenko ₁

Affiliation

The use of water as a donor for hydrogen suitable for the reduction of several important classes of organic compounds is described. It is found that the reductive water splitting can be promoted by several metalloids among which silicon shows the best efficiency. The developed methodologies were applied for the reduction of nitro compounds, N-oxides, sulfoxides, alkenes, alkynes, hydrodehalogenation as well as for the gram-scale synthesis of several substrates of industrial importance.

中文翻译：

硅引发的水分解在减少有机基质中的应用。

描述了使用水作为氢的供体，其适合于还原几种重要类别的有机化合物。发现还原水分解可以通过几种准金属来促进，其中硅显示出最佳的效率。所开发的方法学被用于还原硝基化合物，N-氧化物，亚砜，烯烃，炔烃，加氢脱卤作用以及几种工业上具有重要意义的底物的克级合成。

更新日期：2018-04-25

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