Homogeneous Oxygenase Catalysis,Chemical Reviews

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Homogeneous Oxygenase Catalysis
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-04-09 00:00:00 , DOI: 10.1021/acs.chemrev.7b00193
Yujie Liang ₁ , Jialiang Wei ₁ , Xu Qiu ₁ , Ning Jiao _{1,

2}

Affiliation

Oxygenases-catalyzed reductive activation of molecular oxygen and incorporation of O atoms into an organic molecule is undoubtedly one of the most attractive research areas. Typically, these oxygenation reactions proceed with high selectivity and reactivity, which is seldom found in its “biomimetic” chemocatalytic counterparts. Furthermore, enzymatic oxygenation can avoid undesired overoxidation, which is frequently observed in (industrial) chemical transformation. Therefore, it is not surprising that tremendous attention has been paid to enzymatic oxygenation. Their application in organic synthesis has been steadily growing over the years. The goal of the present Review is to provide a handy reference for chemists interested in using homogeneous oxygenase catalysis and those interested in discovering new types of biomimetic oxidations and oxygenations with dioxygen. In this Review, we will review the recent advances in in homogeneous oxygenase catalysis to reveal the great achievements and potentials in this field.

中文翻译：

均相加氧酶催化

氧合酶催化的分子氧还原活化和O原子掺入有机分子无疑是最有吸引力的研究领域之一。通常，这些氧化反应以高选择性和反应性进行，这在其“仿生”化学催化对应物中很少发现。此外，酶促氧化可以避免不希望的过氧化，这种过氧化通常在（工业）化学转化中观察到。因此，毫不奇怪的是，人们对酶促氧化给予了极大的关注。多年来，它们在有机合成中的应用一直稳定增长。本综述的目的是为对使用均相加氧酶催化感兴趣的化学家以及对发现新型仿生氧化和双氧氧化感兴趣的化学家提供方便的参考。在这篇综述中，我们将回顾均相加氧酶催化的最新进展，以揭示该领域的巨大成就和潜力。

更新日期：2018-04-09

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