Chiral separation and characterization of triazatruxene-based face-rotating polyhedra: the role of non-covalent facial interactions†,Chemical Communications

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Chiral separation and characterization of triazatruxene-based face-rotating polyhedra: the role of non-covalent facial interactions†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-04-09 00:00:00 , DOI: 10.1039/c8cc02049c
Pei Zhang _{1,

2,

3,

4,

5} , Xinchang Wang _{1,

2,

3,

4,

5} , Wei Xuan _{1,

2,

3,

4,

5} , Pixian Peng _{1,

2,

3,

4,

5} , Zhihao Li _{1,

2,

3,

4,

5} , Ruqiang Lu _{1,

2,

3,

4,

5} , Shuang Wu _{1,

2,

3,

4,

5} , Zhongqun Tian _{1,

2,

3,

4,

5} , Xiaoyu Cao _{1,

2,

3,

4,

5}

Affiliation

We constructed a series of novel chiral molecular face-rotating polyhedra (FRP) from two 10,15-dihydro-5H-diindolo[3,2-a:3′,2′-c]carbazole (triazatruxene) derivatives and trans-1,2-cyclohexane diamine, and investigated how facial interactions and the positions of substituents determine the diastereoselectivity and geometry of the final assemblies.

中文翻译：

基于三氮杂卓烯的脸部旋转多面体的手性分离和表征：非共价脸部相互作用的作用†

我们从两个10,15-dihydro-5 H -diindolo [3,2- a：3'，2'- c ]咔唑（triazatruxene）衍生物和反式- 1,2-环己烷二胺，并研究了面部相互作用和取代基的位置如何确定最终装配的非对映选择性和几何形状。

更新日期：2018-04-09

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