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High-temperature order-disorder phase transition in Fe-18Ga alloy evaluated by internal friction method
Journal of Alloys and Compounds ( IF 5.8 ) Pub Date : 2018-04-07
Meng Sun, Xianping Wang, Le Wang, Hui Wang, Weibin Jiang, Wang Liu, Ting Hao, Rui Gao, Yunxia Gao, Tao Zhang, Li Wang, Qianfeng Fang, Changsong Liu

The structure, internal friction (IF) behavior, resistivity and magnetostriction property of Fe-18Ga alloy were systematically analyzed in this investigation. In the IF spectra of Fe-18Ga alloy covered from room temperature (RT) to 800 °C, a prominent IF peak (labeled as Ptr peak) was observed in the high temperature range 530 °C–690 °C besides the reported IF peak related with grain boundary relaxation in the moderate temperature range 400 °C–530 °C. The peak position of Ptr peak hardly changes with measuring frequency, implying that its mechanism is most possibly related with phase transition. Considering from the wide peak shape, Ptr peak can be decomposed into two components: the lower temperature Ptr1 peak located around 530 °C–605 °C and the higher temperature Ptr2 peak located around 605 °C–690 °C. Combined with calculated phase diagram, resistivity and magnetostriction analysis, the mechanism of Ptr peak was suggested to originate from the order-disorder phase transition related with Ga atom distribution in Fe-18Ga alloy: Ptr1 peak was ascribed to D03→B2 transition and Ptr2 peak was ascribed to B2→A2 transition, respectively.



中文翻译:

内摩擦法评价Fe-18Ga合金中高温有序无序相变

本研究对Fe-18Ga合金的组织,内摩擦(IF)行为,电阻率和磁致伸缩性能进行了系统的分析。在从室温(RT)到800°C的Fe-18Ga合金的IF光谱中,除了报道的IF,在530°C–690°C的高温范围内还观察到了显着的IF峰(标记为P tr峰)。在400°C–530°C的中等温度范围内,与晶界弛豫相关的峰。P tr峰值的峰值位置几乎不会随测量频率变化,这表明其机理最可能与相变有关。从宽峰形状考虑,P tr峰可分解为两个分量:较低的温度Ptr1峰值位于530°C–605°C左右,较高的温度P tr2峰值位于605°C–690°C左右。结合计算出的相图,电阻率和磁致伸缩分析,认为P tr峰的机理起源于与Fe-18Ga合金中Ga原子分布有关的有序-无序相变:P tr1峰归因于D0 3 →B2跃迁和P TR2峰分别归属于B2→A2过渡。

更新日期:2018-04-08
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