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Effect of SnO2 on the structure and catalytic performance of Co3O4 for N2O decomposition
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-04-07
Yongzhao Wang, Xiaobo Hu, Ke Zheng, Xuhui Wei, Yongxiang Zhao

The scope of this study was to investigate the effect of SnO2 addition on the structure and catalytic performance of Co3O4 for N2O decomposition. SnO2-Co3O4 exhibits much better catalytic activity in the absence or presence of water vapor than Co3O4. Spectroscopic characterization of SnO2-Co3O4 showed that this solid possesses higher degree of Co dispersion, smaller Co3O4 particles and larger SBET due to the addition of SnO2. In addition, an interaction between Sn and Co oxides formed at the SnO2/Co3O4 interface promotes the electron donation ability of Co2+ and facilitates desorption of surface oxygen species, which might be considered as an important factor that contributes to the excellent catalytic performance of SnO2-Co3O4 for N2O decomposition.



中文翻译:

SnO 2对Co 3 O 4的结构和催化N 2 O分解性能的影响

这项研究的范围是调查SnO的效果2添加对Co的结构和催化性能3 ø 4对于N 2 ö分解。SnO 2 -Co 3 O 4在不存在或存在水蒸气的情况下表现出比Co 3 O 4更好的催化活性。SnO 2 -Co 3 O 4的光谱表征表明,由于添加了SnO 2,该固体具有较高的Co分散度,较小的Co 3 O 4颗粒和较大的S BET。另外,在SnO 2 / Co 3 O 4界面处形成的Sn和Co氧化物之间的相互作用促进了Co 2+的电子给体能力,并促进了表面氧的解吸,这可能被认为是导致表面氧物种的重要因素。 SnO 2 -Co 3 O 4对N 2 O分解具有优异的催化性能。

更新日期:2018-04-08
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