A new hybrid compound formulated as [Fe₃F₈(H₂O)₂](Am₂TAZ)₂ (Am₂TAZ= 3,5-diamino-1,2,4-triazole) was prepared under hydrothermal conditions. The crystal structure was solved by single-crystal X-ray diffraction and the bulk was characterized by thermal analyses (TG-MS), vibrational spectroscopy (FTIR, Raman), Ultraviolet-visible spectroscopy (UV–Vis), and scanning electron microscopy (SEM-EDX). It crystallizes in the triclinic system space group P $\bar{1}$ with unit cell parameters a= 7.100(2) Å, b= 7.658(2) Å, c= 8.321(2) Å, α = 107.330(20)°, β = 111.842(18)°, γ = 93.049(17)°, Z = 1 and V= 394.01(17) ų. The studied X-ray crystal structure shows the two oxidation states for iron atoms (Fe²⁺, Fe³⁺) and generates a 2D inorganic network, built up of inorganic layers constructed from infinite inorganic chains running along a axis. In fact, these chains are connected via (Fe³⁺(3)F₆) octahedral. OW-H^…F and N-H^…F hydrogen bonds, making up the whole 3D network, are strongly linked in the layers. Magnetization measurements were performed, exhibiting the paramagnetic feature of the studied compound above 150 K.

在水热条件下制备了一种新的杂化化合物，其配制为[Fe ₃ F ₈（H ₂ O）₂ ]（Am ₂ TAZ）₂（Am ₂ TAZ = 3,5-二氨基-1,2,4-三唑）。晶体结构通过单晶X射线衍射解析，并通过热分析（TG-MS），振动光谱法（FTIR，Raman），紫外可见光谱法（UV-Vis）和扫描电子显微镜（ SEM-EDX）。它在三斜晶系空间群P中结晶$\overline{\mathrm{1个}}$晶胞参数a = 7.100（2）Å，b = 7.658（2）Å，c = 8.321（2）Å，α= 107.330（20）°，β= 111.842（18）°，γ= 93.049（17） °，Z = 1和V = 394.01（17）埃³。研究的X射线晶体结构显示了铁原子的两个氧化态（Fe 2 ⁺，Fe ³⁺），并生成2D无机网络，该网络由沿轴延伸的无限无机链构成的无机层组成。实际上，这些链是通过（Fe ³⁺（3）F ₆）八面体连接的。OW-H ^… F和NH ^…构成整个3D网络的F氢键在各层中紧密相连。进行了磁化测量，显示了所研究化合物在150 K以上的顺磁特征。