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Analysis of quasi-reversible cyclic voltammograms: Transformation to scan-rate independent form
Electrochemistry Communications ( IF 4.7 ) Pub Date : 2018-04-06
Tamás Pajkossy

A simple procedure is suggested by which cyclic voltammograms, CVs, pertaining to partially diffusion controlled charge transfer reactions can be analyzed. Using this procedure, from a set of CVs taken at varied scan rates, two scan-rate independent, hysteresis-free functions can be calculated. One of them is the diffusion-free polarization curve, the other is the semi-integrated form of the reversible CV.



中文翻译:

准可逆循环伏安图分析:转换为扫描速率独立形式

提出了一种简单的程序,通过该程序可以分析与部分扩散控制的电荷转移反应有关的循环伏安图CV。使用此程序,可以从以不同扫描速率获取的一组CV中计算出两个独立于扫描速率,无滞后的函数。其中一个是无扩散极化曲线,另一个是可逆CV的半积分形式。

更新日期:2018-04-07
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