Supramolecular assemblies of dinuclear alkynylplatinum(ii) terpyridine complexes with double-decker silsesquioxane nano-cores: the role of isomerism in constructing nano-structures†,Chemical Communications

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Supramolecular assemblies of dinuclear alkynylplatinum(ii) terpyridine complexes with double-decker silsesquioxane nano-cores: the role of isomerism in constructing nano-structures†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-04-06 00:00:00 , DOI: 10.1039/c8cc00557e
Ho-Leung Au-Yeung _{1,

2,

3,

4} , Sammual Yu-Lut Leung _{1,

2,

3,

4} , Vivian Wing-Wah Yam _{1,

2,

3,

4}

Affiliation

Isomeric double-decker silsesquioxane-functionalized dinuclear alkynylplatinum(II) terpyridine complexes demonstrate self-association behaviours via the stabilisation of hydrophobic, Pt⋯Pt and/or π–π stacking interactions. These supramolecular architectures and molecular packings are found to be closely related to the isomeric configurations of the complexes and have been investigated using various spectroscopic studies.

中文翻译：

具有双倍倍半硅氧烷纳米核的双核炔基铂（ii）联吡啶复合物的超分子组装：异构体在构建纳米结构中的作用†

同级双层倍半硅氧烷官能化的双核炔基铂（II）吡啶吡啶配合物通过疏水，Pt⋯Pt和/或π-π堆积相互作用的稳定作用表现出自缔合行为。发现这些超分子结构和分子堆积与复合物的异构体构型密切相关，并且已经使用各种光谱学研究进行了研究。

更新日期：2018-04-06

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