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Removal of nitrate from water by the electrocatalytic denitrification on the Cu-Bi electrode
Journal of Electroanalytical Chemistry ( IF 4.5 ) Pub Date : 2018-04-05
Weichun Gao, Lulu Gao, Dan Li, Kaituo Huang, Li Cui, Jing Meng, Jiyan Liang

The Cu-Bi cathode was a new type of electrode in the field of electrocatalytic denitrification. The Cu-Bi electrode prepared by electrodeposition at the current density of 6 mA cm−2 was better. The Cu-Bi coating was compact and crystalline by the characterization of SEM, EDS and XRD. Reduction of nitrate was investigated on Cu-Bi cathodes and Ti/Ru-IrO2 anodes. For 100 mg L−1 NO3-N, the highest NO3-N removal rate of 87.5% was obtained at the current density of 6 mA cm−2 and in neutral electrolyte at 4 h. The removal of nitrate on Cu-Bi electrodes was better in neutral electrolyte, which didn't require additional acid or alkali to adjust pH. When the initial concentration of NO3-N was 50 mg L−1, the effluent concentration of NO3-N at 4 h was 7.175 mg L−1 lower than the level of drinking water on the standard of the World Health Organization (WHO, 10 mg L−1). The kinetic investigation showed that the reduction of nitrate on Cu-Bi displayed pseudo first-order kinetic behavior. The results of Cyclic Voltammetric (CV) measurements indicated that nitrate was reduced on the Cu-Bi electrode with the occurrence of the hydrogen evolution.



中文翻译:

Cu-Bi电极上的电催化反硝化去除水中的硝酸盐

Cu-Bi阴极是电催化反硝化领域中的一种新型电极。通过电沉积以6mA cm -2的电流密度制备的Cu-Bi电极更好。通过SEM,EDS和XRD的表征,Cu-Bi涂层致密且结晶。在Cu-Bi阴极和Ti / Ru-IrO 2阳极上研究了硝酸盐的还原。对于100 mg L -1 NO 3 -- N,在6 mA cm -2的电流密度下,最高NO 3 -- N去除率达到87.5%。并在4小时内置于中性电解液中。在中性电解液中,Cu-Bi电极上的硝酸盐去除效果更好,不需要额外的酸或碱来调节pH。当NO 3 -- N的初始浓度为50 mg L -1时,在4 h时NO 3 -- N的废水浓度比世界卫生组织标准的饮用水水平低7.175 mg L -1。(WHO,10mg L -1)。动力学研究表明,硝酸盐在Cu-Bi上的还原表现出拟一级动力学行为。循环伏安法(CV)的测量结果表明,随着析氢的发生,硝酸铜在Cu-Bi电极上被还原。

更新日期:2018-04-06
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