In this account, we summarize our recent efforts in the total syntheses of several indole alkaloids, including minfiensine, calophyline A, deformylcorymine, strictamine, and goniomitine. Our central theme is to utilize skeletal rearrangements as key strategies for generating complex structures. 1 Introduction 2 The Development of an Aza-Pinacol Rearrangement 3 Applications of Aza-Pinacol Rearrangements in Total ­Syntheses 4 Strategy Extension: The Total Synthesis of Goniomitine 5 Conclusion

中文翻译：

---

骨架重排作为吲哚生物碱全合成策略

在这篇文章中，我们总结了我们最近在几种吲哚生物碱的全合成方面所做的努力，包括 minfiensine、calophyline A、去甲酰可碱、严格胺和 goniomitine。我们的中心主题是利用骨架重排作为生成复杂结构的关键策略。1 引言 2 Aza-Pinacol 重排的发展 3 Aza-Pinacol 重排在全合成中的应用 4 策略扩展：Goniomitine 的全合成 5 结论