Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]†‡,Inorganic Chemistry Frontiers

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Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]†‡
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2018-04-04 00:00:00 , DOI: 10.1039/c8qi00174j
Frédéric Guégan _{1,

2,

3,

4,

5} , François Riobé _{1,

2,

6,

7,

8} , Olivier Maury _{1,

2,

6,

7,

8} , Julie Jung _{3,

9,

10,

11,

12} , Boris Le Guennic _{3,

9,

10,

11,

12} , Christophe Morell _{1,

2,

5,

12,

13} , Dominique Luneau _{1,

2,

3,

4,

5}

Affiliation

We report the luminescence and magnetic properties of the mononuclear Dy(III) complex [DyTp₂Acac] (Tp = tris-pyrazolylborohydride and Acac = 2,4-pentanedionate). This complex displays peculiar slow magnetisation dynamics at low temperature in the absence of a static field, which we managed to interpret using its resolved luminescence spectrum and ab initio calculations.

中文翻译：

教老分子的新招数：证据和[DyTp缓慢磁化动力学的合理化₂ ACAC] † ‡

我们报告了单核Dy（III）配合物[DyTp ₂ Acac]（Tp = tris-pyrazolylborohydride和Acac = 2,4-pentanedateate）的发光和磁性。在没有静态磁场的情况下，这种复合物在低温下显示出奇特的慢磁化动力学，我们设法使用其解析的发光光谱和从头算来解释。

更新日期：2018-04-04

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