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Tunable Prussian blue analogues for the selective synthesis of propargylamines through A3 coupling†
Catalysis Science & Technology ( IF 4.4 ) Pub Date : 2018-04-04 00:00:00 , DOI: 10.1039/c8cy00073e
Carlos Marquez 1, 2, 3, 4 , Francisco G. Cirujano 1, 2, 3, 4 , Cédric Van Goethem 1, 2, 3, 4 , Ivo Vankelecom 1, 2, 3, 4 , Dirk De Vos 1, 2, 3, 4 , Trees De Baerdemaeker 1, 2, 3, 4
Affiliation  

M1[Co(CN)6]2/3-type Prussian blue analogues (M1–Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86Zn0.14–Co PBA was the best catalyst for the reaction by combining the high conversion obtained with Cu–Co PBA with the excellent selectivity obtained with Zn–Co PBA.

中文翻译:

可调谐的普鲁士蓝类似物,可通过A 3偶联选择性地合成炔丙胺

研究了M 1 [Co(CN)6 ] 2/3型普鲁士蓝类似物(M 1 -Co PBAs)作为通过苯乙炔,苯甲醛和哌啶的A 3偶联合成炔丙基胺的催化剂。Cu 0.86 Zn 0.14 -Co PBA通过将Cu-Co PBA获得的高转化率与Zn-Co PBA获得的优异的选择性相结合,是反应的最佳催化剂。
更新日期:2018-04-04
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