Towards Useful Boronates through Atom‐Economical Catalyzed Cascade Reactions,Chemistry - A European Journal

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Towards Useful Boronates through Atom‐Economical Catalyzed Cascade Reactions
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-06-25 , DOI: 10.1002/chem.201800659
Elena Buñuel ₁ , Diego J. Cárdenas ₁

Affiliation

Metal‐catalyzed borylative cyclization reactions of polyunsaturated compounds allow concomitant formation of C−C and C−B bonds to provide cyclic boronates, which constitute synthetically useful intermediates. Recent developments using first‐row transition metals as catalysts provide fully atom‐economical reactions that follow mechanisms involving σ‐bond metathesis.

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