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Molecular Clusters: Nanoscale Building Blocks for Solid-State Materials
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-03-31 00:00:00 , DOI: 10.1021/acs.accounts.8b00016 Andrew Pinkard 1 , Anouck M. Champsaur 1 , Xavier Roy 1
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-03-31 00:00:00 , DOI: 10.1021/acs.accounts.8b00016 Andrew Pinkard 1 , Anouck M. Champsaur 1 , Xavier Roy 1
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The programmed assembly of nanoscale building blocks into multicomponent hierarchical structures is a powerful strategy for the bottom-up construction of functional materials. To develop this concept, our team has explored the use of molecular clusters as superatomic building blocks to fabricate new classes of materials. The library of molecular clusters is rich with exciting properties, including diverse functionalization, redox activity, and magnetic ordering, so the resulting cluster-assembled solids, which we term superatomic crystals (SACs), hold the promise of high tunability, atomic precision, and robust architectures among a diverse range of other material properties.
中文翻译：
分子簇：固态材料的纳米构建基块
将纳米级构建基元编程组装成多组分层次结构，是自下而上构建功能材料的强大策略。为了发展这一概念，我们的团队探索了将分子团簇用作超原子构建基块来制造新型材料的方法。分子簇库具有令人兴奋的特性，包括各种功能化，氧化还原活性和磁有序性，因此所得的簇组装固体（我们称其为超原子晶体（SAC））具有很高的可调谐性，原子精度和各种其他材料特性中的强大体系结构。
更新日期：2018-03-31
中文翻译：
分子簇：固态材料的纳米构建基块
将纳米级构建基元编程组装成多组分层次结构，是自下而上构建功能材料的强大策略。为了发展这一概念，我们的团队探索了将分子团簇用作超原子构建基块来制造新型材料的方法。分子簇库具有令人兴奋的特性，包括各种功能化，氧化还原活性和磁有序性，因此所得的簇组装固体（我们称其为超原子晶体（SAC））具有很高的可调谐性，原子精度和各种其他材料特性中的强大体系结构。
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