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Sobralene, a new sex-aggregation pheromone and likely shunt metabolite of the taxadiene synthase cascade, produced by a member of the sand fly Lutzomyia longipalpis species complex
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-03-30 , DOI: 10.1016/j.tetlet.2018.03.088 Matthew J Palframan 1 , Krishna K Bandi 2 , James G C Hamilton 2 , Gerald Pattenden 1
中文翻译：
Sobralene，一种新的性聚集信息素，可能是紫杉二烯合酶级联的分流代谢物，由白蛉 Lutzomyia longipis 物种复合体的成员产生
更新日期：2018-03-30
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-03-30 , DOI: 10.1016/j.tetlet.2018.03.088 Matthew J Palframan 1 , Krishna K Bandi 2 , James G C Hamilton 2 , Gerald Pattenden 1
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A new sex-aggregation pheromone, sobralene, produced by the sand fly Lutzomyia longipalpis from Sobral (Ceará State, Brazil) is shown to have the novel 6,12-membered ring-fused diterpene structure 3. It is proposed that sobralene is a likely shunt metabolite of the taxadiene synthase-catalysed cyclisation of geranygeranyl diphosphate.
中文翻译：
Sobralene，一种新的性聚集信息素，可能是紫杉二烯合酶级联的分流代谢物，由白蛉 Lutzomyia longipis 物种复合体的成员产生
一种新的性聚集信息素，sobralene，由来自 Sobral（巴西塞阿拉州）的白蛉Lutzomyia longipalpis产生，具有新颖的 6,12 元环稠合二萜结构3。有人提出，sobralene 可能是一种紫杉二烯合酶催化香叶香叶基二磷酸环化的分流代谢物。
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