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Sobralene, a new sex-aggregation pheromone and likely shunt metabolite of the taxadiene synthase cascade, produced by a member of the sand fly Lutzomyia longipalpis species complex
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-03-30 , DOI: 10.1016/j.tetlet.2018.03.088
Matthew J Palframan 1 , Krishna K Bandi 2 , James G C Hamilton 2 , Gerald Pattenden 1
Affiliation  

A new sex-aggregation pheromone, sobralene, produced by the sand fly Lutzomyia longipalpis from Sobral (Ceará State, Brazil) is shown to have the novel 6,12-membered ring-fused diterpene structure 3. It is proposed that sobralene is a likely shunt metabolite of the taxadiene synthase-catalysed cyclisation of geranygeranyl diphosphate.



中文翻译:

Sobralene,一种新的性聚集信息素,可能是紫杉二烯合酶级联的分流代谢物,由白蛉 Lutzomyia longipis 物种复合体的成员产生

一种新的性聚集信息素,sobralene,由来自 Sobral(巴西塞阿拉州)的白蛉Lutzomyia longipalpis产生,具有新颖的 6,12 元环稠合二萜结构3。有人提出,sobralene 可能是一种紫杉二烯合酶催化香叶香叶基二磷酸环化的分流代谢物。

更新日期:2018-03-30
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