当前位置: X-MOL 学术J. Solid State Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Magnetic Studies on Eu3MO7 (M = Nb, Ta, Ir) with Fluorite-related Structure by 151Eu Mössbauer Spectroscopy and Magnetic Susceptibility Measurements
Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2018-03-22 , DOI: 10.1016/j.jssc.2018.03.024
Yukio Hinatsu , Yoshihiro Doi , Makoto Wakeshima

Magnetic properties of europium-containing compounds Eu3MO7 (M = Nb, Ta, Ir) with fluorite-related structure have been investigated. Magnetic susceptibility measurements show that all these compounds are paramagnetic and have no magnetic ordering down to 1.8 K. At very low temperatures (T<50 K), the susceptibilities of each compound attain constant values, which is characteristic of the ground state for Eu3+ ions. The results of 151Eu Mössbauer spectroscopic measurements show that the asymmetric parameter for Eu(2) in seven-coordination is much larger than that for Eu(1) in cubic environment, which in accordance with the crystallographic result.



中文翻译:

151 EuMössbauer光谱和磁化率测量对与萤石相关结构的Eu 3 M O 7M = Nb,Ta,Ir)的磁性研究

研究了具有萤石相关结构的含euro化合物Eu 3 M O 7M = Nb,Ta,Ir)的磁性能。磁化率测量表明,所有这些化合物都是顺磁性的,并且在低至1.8 K时无磁序。在非常低的温度(T <50 K)下,每种化合物的磁化率均达到恒定值,这是Eu 3基态的特征+离子。结果151个的Eu穆斯堡尔光谱测量表明,对于铕(2)在七协调不对称参数是远大于为铕(1)在立方体环境,其根据所述结晶的结果。

更新日期:2018-03-30
down
wechat
bug