Two neodymium(III) fluorou ternary complexes, [Nd(C₅H₂F₆O₂)₃(C₁₈H₁₅OP)₂] (C₅H₂F₆O₂ = hexafluoroacetylacetone, C₁₈H₁₅OP = triphenylphosphine oxide) (1) and [Nd(C₅H₂F₆O₂)₃(C₁₂H₂₄N₃O₄P)₂] (C₅H₂F₆O₂ = hexafluoroacetylacetone, C₁₂H₂₄N₃O₄P) = tri(4-morphollno) phosphine oxide) (2) have been synthesized by mild condition. The single crystals suitable for X-ray measurement were obtained and the structures of the two complexes were determined by X-ray diffraction in solid states. Single crystal analysis revealed that the two complexes were both eight-coordinated with one central Nd ion and eight O atoms from ligands. They were crystallized in monoclinic symmetry with P2₁/c and monoclinic symmetry C2/c space group, respectively. The complexes were characterized by IR-spectroscopy, thermogravimetric, elemental analyses and fluorescent. In fluorescence spectra, the two complexes both exhibit characteristic neodymium-centered emission.

两种钕（III）氟三元络合物，[Nd（C ₅ H ₂ F ₆ O ₂）₃（C ₁₈ H ₁₅ OP）₂ ]（C ₅ H ₂ F ₆ O ₂ =六氟乙酰丙酮，C ₁₈ H ₁₅ OP =三苯基膦氧化物）（1）和[Nd（C ₅ H ₂ F ₆ O ₂）₃（C ₁₂ H ₂₄ N ₃ O ₄ P）₂ ]（C通过温和的条件合成了₅ H ₂ F ₆ O ₂＝六氟乙酰丙酮，C ₁₂ H ₂₄ N ₃ O ₄ P）＝三（4-吗啉代）氧化膦（2）。获得了适合于X射线测量的单晶，并且通过固态的X射线衍射确定了两种络合物的结构。单晶分析表明，这两个配合物都与一个中心的Nd离子和来自配体的八个O原子八配位。它们与P2 ₁单斜对称结晶/ c和单斜对称C2 / c空间群。通过红外光谱，热重分析，元素分析和荧光对复合物进行表征。在荧光光谱中，这两种配合物均表现出以钕为中心的特征发射。