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Conversion of CO 2 into liquid hydrocarbons in the presence of a Co-containing catalyst based on the microporous metal-organic framework MIL-53(Al)
Fuel Processing Technology ( IF 7.2 ) Pub Date : 2018-07-01 , DOI: 10.1016/j.fuproc.2018.03.016
A.L. Tarasov , V.I. Isaeva , O.P. Tkachenko , V.V. Chernyshev , L.M. Kustov

Abstract A novel 10%Co/MIL-53(Al) nanohybrid based on the microporous metal-organic framework MIL-53(Al) prepared by MW-assisted synthesis exhibits the properties of a bifunctional catalyst with activity in CO2 hydrogenation to CO and consecutive synthesis of liquid hydrocarbons from carbon monoxide formed. The observed increase in the CO2 conversion in comparison with the thermodynamically possible conversion is assumed to be due to the expected shift of the equilibrium toward the formation of CO as a result of its further rapid conversion to hydrocarbons by the Fisher-Tropsch reaction.

中文翻译:

在基于微孔金属有机骨架 MIL-53(Al) 的含 Co 催化剂存在下将 CO 2 转化为液态烃

摘要 一种基于微孔金属-有机骨架 MIL-53(Al) 的新型 10%Co/MIL-53(Al) 纳米杂化物,通过 MW 辅助合成,展现了双功能催化剂的性质,在 CO2 加氢生成 CO 和由形成的一氧化碳合成液态烃。与热力学上可能的转化率相比,观察到的 CO2 转化率的增加被认为是由于通过费托反应进一步快速转化为碳氢化合物,平衡向形成 CO 的预期移动。
更新日期:2018-07-01
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