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A high-valent di-μ-oxo dimanganese complex covalently anchored in a metal–organic framework as a highly efficient and recoverable water oxidation catalyst†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-03-29 00:00:00 , DOI: 10.1039/c8cc00258d
Lina Zhang 1, 2, 3, 4, 5 , Junying Chen 1, 2, 3, 4, 5 , Ting Fan 1, 2, 3, 4, 5 , Kui Shen 1, 2, 3, 4, 5 , Miao Jiang 1, 2, 3, 4, 5 , Yingwei Li 1, 2, 3, 4, 5
Affiliation  

A biomimetic di-μ-oxo dimanganese complex bearing two triazole-binding tridentate ligands is successfully anchored inside a metal–organic framework (MOF) through a covalent-functionalization-assisted coordination strategy, exhibiting high activity and reliable durability in the chemical water oxidation reaction.

中文翻译:

高价位的二-μ-氧代二锰配合物,共价锚固在金属-有机骨架中,是一种高效且可回收的水氧化催化剂

带有两个三唑结合三齿配体的仿生二μ-氧代二锰复合物通过共价官能化辅助配位策略成功锚固在金属-有机骨架(MOF)中,在化学水氧化反应中表现出高活性和可靠的耐久性。
更新日期:2018-03-29
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