Synthetic Transformations of Alkenyl MIDA Boronates toward the Efficient Construction of Organoborons,Synlett

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Synthetic Transformations of Alkenyl MIDA Boronates toward the Efficient Construction of Organoborons
Synlett ( IF 1.7 ) Pub Date : 2018-03-28 , DOI: 10.1055/s-0036-1591958
Honggen Wang ₁ , Yao-Fu Zeng ₂ , Wen-Xin Lv ₁ , Dong-Hang Tan ₁

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The attachment of N -methyliminodiacetyl boron (MIDA boron) to alkenes leads to a new type of activated alkenes. Synthetic manipulation of the alkene double bond while retaining the boron moiety offers an unprecedented opportunity for the construction of organoborons. These reactions feature unique reactivity, good regioselectivity, and they can be used to access organoborons that are historically difficult to prepare. Herein, we give a brief summary of advances in the use of alkenyl MIDA boronates as starting materials for organoboron synthesis. Mechanisms are discussed where relevant.

中文翻译：

烯基MIDA硼酸酯的合成转化以有效构建有机硼

N-甲基亚氨基二乙酰硼（MIDA 硼）与烯烃的连接导致了一种新型的活化烯烃。在保留硼部分的同时合成操纵烯烃双键为构建有机硼提供了前所未有的机会。这些反应具有独特的反应性和良好的区域选择性，可用于获取历史上难以制备的有机硼。在此，我们简要总结了使用烯基 MIDA 硼酸酯作为有机硼合成原料的进展。在相关的地方讨论机制。

更新日期：2018-03-28

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