In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(i) polymer†,Inorganic Chemistry Frontiers

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In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(i) polymer†
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2018-03-28 00:00:00 , DOI: 10.1039/c8qi00205c
Shixiong Li _{1,

2,

3,

4} , Chaohai Wei _{1,

2,

3,

4} , Yun Hu _{1,

2,

3,

4} , Haizhen Wu _{2,

3,

4,

5} , Fusheng Li _{6,

7,

8,

9}

Affiliation

A one-dimensional copper(I) nanorod polymer [Cu(L)₂·(CN)]_n (1) (L = 4(3H)-quinazolone), was formed in situ by C–C bond cleavage of acetonitrile. The in situ synthesis of 1 was analyzed using electron paramagnetic resonance (EPR) spectroscopy and electrospray ionization mass spectrometry (ESI-MS) and its methylene blue (MB) photocatalytic degradation mechanism was revealed from density functional theory (DFT) calculations. The results are helpful for the in situ synthesis of –CN complexes.

中文翻译：

氰基桥联Cu（i）聚合物的原位合成和光催化机理†

一维铜（I）纳米棒聚合物[Cu（L）₂ ·（CN）] _n（1）（L = 4（3 H）-喹唑酮）通过乙腈的CC键裂解原位形成。在原位合成的1使用电子顺磁共振（EPR）波谱法和电喷雾电离质谱（ESI-MS）和它的亚甲基蓝（MB）进行分析的光催化降解机理从密度泛函理论（DFT）计算显示。这些结果有助于原位合成–CN配合物。

更新日期：2018-03-28

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