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Synthesis of MIL-100(Fe)@MIL-53(Fe) as a novel hybrid photocatalyst and evaluation photocatalytic and photoelectrochemical performance under visible light irradiation
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2018-03-17 , DOI: 10.1016/j.jssc.2018.03.018
Soheil Abdpour , Elaheh Kowsari , Mohammad Reza Alavi Moghaddam

The MIL-100(Fe)@MIL-53(Fe) was synthesized by the ultrasound method, while the initial solution for the preparation of the photocatalysts was included nanoparticles of MIL-100(Fe) and a precursor solution for the synthesizing of MIL-53(Fe). After an appropriate time of reaction, nanoparticles of MIL-100(Fe) were decorated on the surface of MIL-53(Fe). Phtoelectrochemical/electrochemical and photocatalytic degradation of methyl orange over MIL-100(Fe)@MIL-53(Fe) were explored. The phtoelectrochemical/electrochemical and photocatalytic performance of the prepared photocatalysts revealed that the introduction of nanoparticles of the MIL-100(Fe) on the surface of MIL-53(Fe) enhanced the photocatalytic performance of the resulted photocatalyst compared to pure MIL-53(Fe) and MIL-100(Fe). The enhanced photocatalytic efficiency is ascribed to increase the visible light region absorption and to decrease the electron-hole recombination rate in the hybrid photocatalyst. The present work demonstrated that the photocatalytic properties of metal organic frameworks (MOFs) can be improved by the fabrication of hybrid photocatalysts based on the different types of MOFs.



中文翻译:

新型杂化光催化剂MIL-100(Fe)@ MIL-53(Fe)的合成及其在可见光照射下的光催化性能和光电化学性能

通过超声法合成MIL-100(Fe)@ MIL-53(Fe),同时包括用于制备光催化剂的初始溶液 MIL-100(Fe)的纳米颗粒和用于合成MIL-53(Fe)的前体溶液。在适当的反应时间后,将MIL-100(Fe)的纳米颗粒装饰在MIL-53(Fe)的表面上。研究了MIL-100(Fe)@ MIL-53(Fe)对甲基橙的光电化学/光催化降解。制备的光催化剂的光电化学/电化学和光催化性能表明,与纯MIL-53(相比),将MIL-100(Fe)纳米颗粒引入MIL-53(Fe)表面可增强所得光催化剂的光催化性能。 Fe)和MIL-100(Fe)。增强的光催化效率归因于增加可见光区域吸收并减少电子-空穴复合杂化光催化剂的速率 本工作表明,可以通过基于不同类型的MOF制备杂化光催化剂来改善金属有机骨架(MOF)的光催化性能。

更新日期:2018-03-27
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