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Highly selective hydrogenation of α, β-unsaturated carbonyl compounds over supported Co nanoparticles
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-03-26 , DOI: 10.1016/j.catcom.2018.03.017
Pengbo Jiang , Xinlin Li , Wenbin Gao , Xiang Wang , Yu Tang , Kai Lan , Bin Wang , Rong Li

A nitrogen-doped porous carbon materials (CPNs) with supported Co nanoparticles ([email protected]) with lamellar structure, high surface area and excellent magnetic properties was synthesized successfully by one-pot method. The [email protected] exhibited an excellent catalytic activity with 99% conversion and selectivity for hydrogenation of furfural (FAL) to furfuryl alcohol (FOL) under the pressure of H2. In addition, the [email protected] were further investigated in the kinetic study and selective hydrogenation of the other α, β unsaturated carbonyl compounds. The study of the [email protected] indicated that it was suitable for selective hydrogenation of the α, β unsaturated carbonyl compounds in the industry.



中文翻译:

负载Co纳米粒子上α,β-不饱和羰基化合物的高度选择性加氢

通过一锅法成功地合成了具有片状结构,高表面积和优异磁性能的负载型Co纳米颗粒(受电子邮件保护)的氮掺杂多孔碳材料(CPNs)。[受电子邮件保护]具有出色的催化活性,在H 2压力下,糠醛(FAL)氢化为糠醇(FOL)的转化率为99%。此外,在动力学研究和其他α,β不饱和羰基化合物的选择性加氢中进一步研究了[电子邮件保护的]。对[电子邮件保护的]的研究表明,它适用于工业中α,β不饱和羰基化合物的选择性加氢。

更新日期:2018-03-26
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