Carbonylative coupling of N-chloroamines with alcohols: synthesis of esterification reagents†,Organic & Biomolecular Chemistry

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Carbonylative coupling of N-chloroamines with alcohols: synthesis of esterification reagents†
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2018-03-26 00:00:00 , DOI: 10.1039/c8ob00462e
Zhiping Yin _{1,

2,

3} , Zechao Wang _{1,

2,

3} , Xiao-Feng Wu _{1,

2,

3}

Affiliation

Herein we report a new method for the carbonylative synthesis of carbamates. Starting from N-chloroamines and alcohols, with copper or Pd/C as the catalyst, the corresponding carbamates were produced in moderate to good yields. No additional oxidant or base is needed in this system. Notably, the produced benzotriazole-carboxylates can be used as esterification reagents.

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