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Direct arylation of tertiary amines via aryne intermediates using diaryliodonium salts
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-03-26 , DOI: 10.1016/j.tetlet.2018.03.067 Zhiang Zhang , Xunshen Wu , Jianwei Han , Wenjun Wu , Limin Wang
中文翻译:
使用二芳基碘鎓盐经芳烃中间体直接芳基化叔胺
更新日期:2018-03-26
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-03-26 , DOI: 10.1016/j.tetlet.2018.03.067 Zhiang Zhang , Xunshen Wu , Jianwei Han , Wenjun Wu , Limin Wang
With a strategy by using diaryliodonium salts as the precursors of benzynes, direct N-arylation of tertiary amines with diaryliodonium salts was reported. Thus, the desired aromatic tertiary amines with a wide range of substituents were synthesized in moderate to excellent yields of 55–91%.
中文翻译:
使用二芳基碘鎓盐经芳烃中间体直接芳基化叔胺
通过使用二芳基碘鎓盐作为苯并炔的前体的策略,已报道了叔胺与二芳基碘鎓盐的直接N-芳基化。因此,合成了所需的具有广泛取代基的芳族叔胺,产率中等至55-91%。