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Photochromism and the fluorescence properties of bisbenzothienylethene and S,S,S′,S′-tetraoxide derivatives with dual conjugated fluorescent groups on their side chains†
Photochemical & Photobiological Sciences ( IF 3.1 ) Pub Date : 2018-03-23 00:00:00 , DOI: 10.1039/c8pp00050f
Katsuhiro Watanabe 1, 2, 3, 4, 5 , Takashi Ubukata 1, 2, 3, 4, 5 , Yasushi Yokoyama 1, 2, 3, 4, 5
Affiliation  

Two photochromic bisbenzothienylethenes with two fluorescent (4-((2,5-bis(dodecyloxy)-4-(phenylethynyl)phenyl)ethynyl)phenyl) units and their disulfone derivatives were synthesized, and their photochromic and fluorescence properties were examined. Bisbenzothienylethenes showed photochromism and turn-off type fluorescence by UV-light irradiation, while their disulfone derivatives showed turn-on type fluorescence and the one-way isomerization to the closed form.

中文翻译:

光致变色和bisbenzothienylethene的荧光特性和小号小号小号',小号'与它们的侧链双共轭的荧光基团-tetraoxide衍生物

合成了具有两个荧光(4-((2,5-双(十二烷基氧基)-4-(苯基乙炔基)苯基)乙炔基)苯基)单元的两个光致变色双苯并噻吩基乙烯及其二砜衍生物,并对其光致变色和荧光性质进行了研究。双苯并噻吩基乙烯通过紫外线照射显示出光致变色和关闭型荧光,而它们的二砜衍生物显示了打开型荧光和单向异构化为封闭形式。
更新日期:2018-03-23
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