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Zn-doped hematite modified by graphene-like WS2: A p-type semiconductor hybrid photocathode for water splitting to produce hydrogen
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2018-03-22 , DOI: 10.1016/j.ijhydene.2018.02.152
Dongmei Chu , Kezhen Li , Aijuan Liu , Jie Huang , Chunyong Zhang , Ping Yang , Yukou Du , Cheng Lu

A p-type Zn-doped hematite (α-Fe2O3(Zn)) in spindle-shape with an acceptor density of ca. 4.21 × 1018 cm−3 were synthesized by a facile hydrothermal method. After α-Fe2O3(Zn) was modified with graphene-like WS2 (α-Fe2O3(Zn)/WS2), the photoelectrochemical performances of the composite can be further enhanced. A photocell composed of the p-type α-Fe2O3(Zn)/WS2 nanocomposite as photocathode and n-type α-Fe2O3 as photoanode was assembled to estimate the photocatalytic activity of α-Fe2O3(Zn)/WS2. The amount of the hydrogen and oxygen produced from this tandem cell with the optimal electrodes under 2 h simulated solar light irradiation is 12.5 μmol and 4.3 μmol, respectively.



中文翻译:

类石墨烯WS 2修饰的掺锌赤铁矿:p型半导体杂化光阴极,用于水分解产生氢

p型掺杂Zn的赤铁矿(α-的Fe 2 ö 3(Zn)的)的纺锤形用约的受主密度 通过简便的水热法合成了4.21×10 18  cm -3。后的α-Fe 2 ö 3(锌)与石墨烯状WS改性2(的α-Fe 2 ö 3(Zn)的/ WS 2),该复合材料的光电化学性能可以进一步提高。在p型的α-Fe的组成的光电池2 ö 3(Zn)的/ WS 2纳米复合材料作为光电阴极和n型的α-Fe 2 ö 3作为光电阳极组装来估计的α-Fe的光催化活性2 ö 3(Zn)的/ WS 2。在2 h模拟太阳光照射下,带有最佳电极的串联电池产生的氢气和氧气的量分别为12.5μmol和4.3μmol。

更新日期:2018-03-22
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