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Double spin transition in a two dimensional Fe(ii) coordination network†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-22 00:00:00 , DOI: 10.1039/c8cc01621f
Marek Weselski 1, 2, 3, 4 , Maria Książek 4, 5, 6, 7 , Dominika Rokosz 1, 2, 3, 4 , Agnieszka Dreczko 1, 2, 3, 4 , Joachim Kusz 4, 5, 6, 7 , Robert Bronisz 1, 2, 3, 4
Affiliation  

In the two dimensional network [Fe(ebbtr)2(CH3CN)2](ClO4)2·4CH3CN a sequence of LS → HS → LS → HS transitions occurs as the exclusive result of the change in temperature. This property results from the extraordinary flexibility/elasticity manifested in the hierarchical arrangement of structural events involving the reorientation of coordinated/noncoordinated molecules as well as with the deformation and the mutual shift of the polymeric units.

中文翻译:

二维Fe(ii)配位网络中的双自旋跃迁

在二维网络[Fe(ebbtr)2(CH 3 CN)2 ](ClO 42 ·4CH 3 CN中,由于温度变化的唯一结果,出现了LS→HS→LS→HS跃迁的序列。这种性质是由于结构事件的分层排列所表现出的非凡的柔韧性/弹性而引起的,这种结构事件涉及配位/不配位分子的重新取向以及聚合物单元的变形和相互移动。
更新日期:2018-03-22
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