Aerial dioxygen activation vs. thiol–ene click reaction within a system†,Chemical Communications

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Aerial dioxygen activation vs. thiol–ene click reaction within a system†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-03-22 00:00:00 , DOI: 10.1039/c8cc01359d
Khokan Choudhuri _{1,

2,

3,

4} , Arkalekha Mandal _{1,

2,

3,

4} , Prasenjit Mal _{1,

2,

3,

4}

Affiliation

Markovnikov or anti-Markovnikov selective thiol–ene click (TEC) reactions and the synthesis of β-hydroxysulfides via aerial dioxygen activation are prevalent C–S bond forming reactions of styrenes and thiophenols. Herein, by choosing appropriate environments using solvents with additives or neat conditions, any one of these three reactions was achieved exclusively in excellent yields.

中文翻译：

系统中的空中双氧活化与硫醇-烯点击反应†

Markovnikov或反Markovnikov选择性硫醇-烯点击（TEC）反应和通过空中双氧活化合成β-羟基硫化物是苯乙烯和硫酚的常见C-S键形成反应。在本文中，通过使用具有添加剂的溶剂或在纯净条件下选择合适的环境，这三个反应中的任何一个仅以优异的收率实现。

更新日期：2018-03-22

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