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Detection of triethylamine with fast response by Al2O3/α-Fe2O3 composite nanofibers
Sensors and Actuators B: Chemical ( IF 8.4 ) Pub Date : 2018-03-21 , DOI: 10.1016/j.snb.2018.03.122
Lanlan Guo , Chong Wang , Xueying Kou , Ning Xie , Fangmeng Liu , Hong Zhang , Xishuang Liang , Yuan Gao , Yanfeng Sun , Xiaohong Chuai , Geyu Lu

Pure α-Fe2O3 nanotubes and a series of Al2O3/α-Fe2O3 composite nanofibers were synthesized via facile electrospinning and subsequent calcination at 500 °C in air for 2 h. The morphologies and nanostructures of these samples were characterized through various experimental techniques. It was found that the composite samples were composed of crystal α-Fe2O3 and amorphous Al2O3. The composite Al2O3/α-Fe2O3 nanofibers have smaller grain size than that of pure α-Fe2O3 nanotubes prepared by the same process. Furthermore, comparative gas sensing investigation between Al2O3/α-Fe2O3 composite nanofibers and pure α-Fe2O3 nanotubes was performed to show the superior sensing properties of the composite samples. When the mass ratio of Al source and Fe source was 1:4, the sensor exhibited the highest response to 100 ppm triethylamine at 250 °C. It is worth noting that the response times were no more than 2 s at operating temperatures ranged from 175 °C to 300 °C. Finally, the related mechanism of gas sensing and the role of Al2O3 in the composite nanofibers were discussed in this paper.



中文翻译:

的Al具有快速响应的三乙胺检测2 ö 3 /的α-Fe 2个ö 3复合纳米纤维

纯的α-Fe 2 ö 3纳米管等一系列的Al 2 ö 3 /的α-Fe 2 ö 3复合纳米纤维在空气中通过静电纺丝容易和随后的煅烧合成在500℃下2小时。通过各种实验技术对这些样品的形貌和纳米结构进行了表征。结果发现,复合样品组成晶体的α-Fe的2 ö 3和无定形的Al 2 ö 3。复合的Al 2 ö 3 /的α-Fe 2 ö 3纳米纤维具有更小的晶粒尺寸比纯的的α-Fe 2通过相同的方法制备O 3纳米管。此外,Al的比较气体感测调查2 ö 3 /的α-Fe 2 ö 3复合纳米纤维和纯的α-Fe 2个ö 3进行纳米管以示出复合材料样品的优异传感特性。当铝源和铁源的质量比为1:4时,传感器在250°C下对100 ppm三乙胺的响应最高。值得注意的是,在175°C至300°C的工作温度下,响应时间不超过2 s。最后,介绍了气体传感的相关机理和Al 2 O 3的作用。 本文讨论了复合纳米纤维中的纳米粒子。

更新日期:2018-03-21
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