Abstract Zhoushan is an island city with booming tourism and service industry, but also has many developed VOCs and/or NOX emission industries. It is necessary to carry out regional VOCs and O3 pollution control in Zhoushan as the only new area owns the provincial economic and social administration rights. Anthropogenic VOCs emission inventories were built based on emission factor method and main emission sources were identified according to the emission inventories. Then, localized VOCs source profiles were built based on in-site sampling and referring to other studies. Furthermore, ozone formation potentials (OFPs) profiles were built through VOCs source profiles and maximum incremental reactivity (MIR) theory. At last, the priority control analysis results showed that industrial processes, especially surface coating, are the key of VOCs and O3 control. Alkanes were the most emitted group, accounting for 58.67%, while aromatics contributed the most to ozone production accounting for 69.97% in total OFPs. n-butane, m/p-xylene, i-pentane, n-decane, toluene, propane, n-undecane, o-xylene, methyl cyclohexane and ethyl benzene were the top 10 VOC species that should be preferentially controlled for VOCs emission control. However, m/p-xylene, o-xylene, ethylene, n-butane, toluene, propene, 1,2,4-trimethyl benzene, 1,3,5-trimethyl benzene, ethyl benzene and 1,2,3-trimethyl benzene were the top 10 VOC species that required preferential control for O3 pollution control.

中文翻译：

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基于舟山市VOCs排放清单和臭氧形成潜势的VOCs排放特征及优先控制分析

摘要 舟山是一个旅游和服务业蓬勃发展的海岛城市，同时也有许多发达的VOCs和/或NOX排放产业。舟山作为唯一拥有省级经济社会管理权的新区，有必要开展区域性VOCs和O3污染治理。基于排放因子法建立人为VOCs排放清单，并根据排放清单确定主要排放源。然后，基于现场采样并参考其他研究，构建了本地化的 VOCs 源概况。此外，臭氧形成电位 (OFP) 剖面是通过 VOC 源剖面和最大增量反应性 (MIR) 理论构建的。最后，优先控制分析结果表明，工业过程，特别是表面涂层，是VOCs和O3控制的关键。烷烃是排放量最大的一类，占 58.67%，而芳烃对臭氧产生的贡献最大，占总 OFP 的 69.97%。正丁烷、间/对二甲苯、异戊烷、正癸烷、甲苯、丙烷、正十一烷、邻二甲苯、甲基环己烷和乙苯是VOCs排放控制应优先控制的前10种VOC物种. 但是，间/对二甲苯、邻二甲苯、乙烯、正丁烷、甲苯、丙烯、1,2,4-三甲基苯、1,3,5-三甲基苯、乙基苯和 1,2,3-三甲基苯是 O3 污染控制需要优先控制的前 10 位 VOC 物种。甲苯、丙烷、正十一烷、邻二甲苯、甲基环己烷和乙苯是VOCs排放控制应优先控制的前10种VOC物种。但是，间/对二甲苯、邻二甲苯、乙烯、正丁烷、甲苯、丙烯、1,2,4-三甲基苯、1,3,5-三甲基苯、乙基苯和 1,2,3-三甲基苯是 O3 污染控制需要优先控制的前 10 位 VOC 物种。甲苯、丙烷、正十一烷、邻二甲苯、甲基环己烷和乙苯是VOCs排放控制应优先控制的前10种VOC物种。但是，间/对二甲苯、邻二甲苯、乙烯、正丁烷、甲苯、丙烯、1,2,4-三甲基苯、1,3,5-三甲基苯、乙基苯和 1,2,3-三甲基苯是 O3 污染控制需要优先控制的前 10 位 VOC 物种。